| Simon | | 1034 | | CGHGSM (1) Bechuanaland. CPD1. Native Private
Source: Roll of the CGHGSM | Cape Police |
| Simpson | A | | Private | CGHGSM (1) Bechuanaland
Source: Roll of the CGHGSM | Prince Alfred's Volunteer Guard |
| Simpson | C E | | Trooper | CGHGSM (1) Bechuanaland
Source: Roll of the CGHGSM | Vryburg Volunteers |
| Simpson | F | | Trooper | CGHGSM (2) Basutoland Transkei
Source: Roll of the CGHGSM | Willoughbys Horse |
| Simpson | H N | 1180 | Private | CGHGSM (1) Bechuanaland. CPD1
Source: Roll of the CGHGSM | Cape Police |
| Sims | J | | Private | CGHGSM (1) Basutoland
Source: Roll of the CGHGSM | DEOVR |
| Sinclair | J W | | Captain | CGHGSM (1) Transkei
Source: Roll of the CGHGSM | Transvaal Horse |
| Sinclair | R | | Private | CGHGSM (1) Bechuanaland
Source: Roll of the CGHGSM | Queenstown Rifle Volunteers |
| Sissison | J | | Captain | CGHGSM (2) Basutoland Transkei
Source: Roll of the CGHGSM | Commissariat Department |
| Skea | A D | | Private | CGHGSM (1) Bechuanaland
Source: Roll of the CGHGSM | Kimberley Rifles |
| Skelton | C | | Private | CGHGSM (1) Basutoland
Source: Roll of the CGHGSM | Cape Mounted Riflemen |
| Skenjana | | | | CGHGSM (1) Bechuanaland. CPD1. Native Private
Source: Roll of the CGHGSM | Cape Police |
| Skenjani | James | | | CGHGSM (1) Bechuanaland. CPD1. Native detective
Source: Roll of the CGHGSM | Cape Police |
| Skey | | 298 | | CGHGSM (1) Bechuanaland. CPD1. Native Private
Source: Roll of the CGHGSM | Cape Police |
| Skidmore | W | | Private | CGHGSM (1) Basutoland
Source: Roll of the CGHGSM | Cape Mounted Riflemen |
| Skinner | J | | Corporal | CGHGSM (2) Basutoland Transkei
Source: Roll of the CGHGSM | Ross Light Horse |
| Skinner | R L | | Private | CGHGSM (1) Bechuanaland. CPD2
Source: Roll of the CGHGSM | Cape Police |
| Skowronek | C S F | | Private | CGHGSM (1) Bechuanaland. CPD2. Special Police
Source: Roll of the CGHGSM | Cape Police |
| Skulpat | | 1129 | | CGHGSM (1) Bechuanaland. CPD1. Native Private
Source: Roll of the CGHGSM | Cape Police |
| Skuse | J C | | Private | CGHGSM (1) Basutoland
Source: Roll of the CGHGSM | Dymes Rifles |
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