| Sherriff | Herbert Daniel | 7965 | Shoeing Smith | Source: Nominal roll in WO127 |
| Shipley | Harold | 3069 | Lance Sergeant | Supernumerary 6 Aug 1900
Source: Nominal roll in WO127 |
| Short | Frank | 1890 | Trooper | Source: Nominal roll in WO127 |
| Short | Thomas | 34036 | Trooper | Discharged 30 Jun1902 at own request
Source: Nominal roll in WO127 |
| Silvester | J F / T G | 9668 | Private | Demise: Killed in action 24 Jan 1900
Place: Spioenkop
Source: In Memoriam by S Watt |
| Silvester | T J | 9668 | Private | Killed at Spion Kop. 24 Jan 1900.
Source: Natal Field Force Casualty Roll, page 233 line 14 |
| Sime | Edward Erskine | 3005 | Corporal | Source: Nominal roll in WO127 |
| Simpson | Tom | 9218 | Trooper | Source: Nominal roll in WO127 |
| Simpson | William | 8757 | Sergeant | Source: Nominal roll in WO127 |
| Skelton | Philip Ralph | 1416 | Trooper | Discharged 30 Apr 1902 at own request
Source: Nominal roll in WO127 |
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